“Single-walled carbon nanotubes are like magic in electrodes where particles have huge volume change—they turn garbage into gold.”
— Prof. Jeff Dahn, NSERC/Tesla Canada Inc. Industrial Research Chair, one of the world’s leading electrochemists. – March, 2025
We founded the single wall nanotube industry and invented the only scalable synthesis technology delivering a consistently high-quality product validated by customers worldwide. Backed by a global team with unmatched expertise, OCSiAl sets the standard.
TUBALL™ single wall carbon nanotubes set a new industry benchmark in silicon anode performance. By forming a robust, long-lasting conductive network, TUBALL™ bridges silicon particles and prevents the structural degradation caused by silicon’s natural volume expansion and cracking during cycling.
The more silicon in the anode, the more essential becomes the use of single wall carbon nanotubes in the design.
In silicon-rich anodes (up to 90% SiOx/SiC), volume expansion becomes a critical challenge. Without a robust conductive network, silicon particles fracture and rapidly lose capacity.
When using traditional additives like carbon black or MWCNTs, silicon anodes swell by up to 160%, causing the conductive network to break down and leading to rapid performance loss.
With TUBALL™ single wall carbon nanotubes, swelling is reduced to just ~20%. The conductive network remains intact.
TUBALL™ BATT H2O is a plug-and-play solution designed for seamless integration into existing lithium-ion battery production lines. It comes as a stable, water-based concentrate compatible with standard slurry mixing, coating, and drying processes — no special equipment or process changes needed. Battery manufacturers can easily upgrade to high-silicon anodes and achieve energy density targets without disrupting current workflows. This makes it a practical, low-risk path to next-generation battery performance.
Material system: LIB Anodes (SiC, Si/O, graphite)
Concentrate carrier: Water, CMC, other
TUBALL™ BATT H2O는 바로 사용할 수 있는 최초의 TUBALL™ 나노튜브 기반 솔루션으로, Si/C 애노드의 핵심 문제를 효율적으로 해결합니다. TUBALL™ 그래핀 나노튜브는 0.05%만으로도 Si/C 애노드의 전도성을 탁월하게 개선합니다. Si/C 애노드에 추가되었을 때, TUBALL™ BATT H2O의 안정적인 초미세 그래핀 나노튜브는 LIB의 충전-방전 과정에서 Si/C 애노드 입자를 완전히 덮고 전기적으로 연결합니다. 이는 EV 제조업체가 요구하는 엄격한 사이클링 조건에서도 가능합니다.
Silicon anodes containing a small amount of SWCNTs (0.5 wt%) show much better stability when operated at a high state of charge, because in this regime they maintain lower impedance and degrade more slowly. The study reveals that carefully choosing the voltage window and lithiation/delithiation depth — together with the presence of SWCNTs in the electrode — can dramatically extend the cycle life of silicon anodes.
They examine how Si–PAA anodes reinforced with a small amount of SWCNTs behave under different voltage windows, focusing on how much the electrode expands and how quickly it degrades. When the silicon is cycled in a milder voltage range—meaning less Si is actually lithiated each cycle—the Si/SWCNT/PAA structure remains far more mechanically stable, leading to over five-fold longer cycle life despite reduced usable capacity.
CNTs mechanically restrain silicon, slow crack growth, and suppress excessive SEI buildup, which dramatically reduces electrode swelling even under high-density, industrial conditions. Because CNTs maintain electrical pathways and prevent particle pulverization far better than carbon black, Si–graphite anodes with CNTs deliver much stronger cycling stability, improved fast-charge performance, and superior low-temperature behavior in full 1 Ah pouch cells.
This paper dissects commercial Si/C composites where sub-nanometer silicon clusters are tightly confined inside a highly microporous carbon matrix, delivering ~2000 mAh g⁻¹ with graphite-like tap density (~1 g cm⁻³) and far less stack swelling than you’d expect from 300% Si expansion. By combining detailed nanostructural analysis (Debye XRD, TEM, BET) with operando stack-pressure measurements in pouch cells, it shows how this confinement suppresses cracking and irreversible stack growth, making high-Si anodes behave like something you could actually commercialize.
SWCNTs keep Si and SiO particles electrically connected as they expand and contract, preventing isolation and early capacity loss. Even tiny amounts of nanotubes strengthen the electrode enough that simple CMC/SBR binders work well, and high-loading Si/graphite composites cycle far more stably. Their mechanical flexibility and long, web-like structure make SWCNTs the key element that stabilizes these high-energy anodes.
SWCNTs act as the electrical “glue” that keeps Si/graphite composite anodes connected even as the silicon repeatedly expands and contracts. In these pouch-cell tests, the nanotubes prevent active-mass loss and keep the anode structurally coherent, so the main failure mode is no longer particle isolation—but steady lithium loss into a continually growing SEI. In other words, SWCNTs successfully stabilize the electrode; the remaining degradation comes from electrolyte-driven SEI growth, not from the anode falling apart.
